- CasNo 89-39-4
- Purity 99%
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Buy Good Quality 1,4-DIMETHOXY-2-NITROBENZENE 89-39-4 with a minimum purity of 99%
- Molecular Formula: C8H9 N O4
- Molecular Weight: 183.164
- Vapor Pressure: 0.000698mmHg at 25°C
- Melting Point: 72 °C
- Refractive Index: 1.5310 (estimate)
- Boiling Point: 169 °C / 13mmHg
- Flash Point: 156.7°C
- PSA： 64.28000
- Density: 1.226g/cm3
- LogP: 2.13520
1,4-DIMETHOXY-2-NITROBENZENE(Cas 89-39-4) Usage
|
Synthesis Reference(s) |
Synthetic Communications, 16, p. 681, 1986 DOI: 10.1080/00397918608057740 |
InChI:InChI=1/C8H9NO4/c1-12-6-3-4-8(13-2)7(5-6)9(10)11/h3-5H,1-2H3
89-39-4 Relevant articles
Metal-free Transformations of Nitrogen-Oxyanions to Ammonia via Oxoammonium Salt
Anju, Balakrishnan S.,Kundu, Subrata,Mondal, Aditesh,Sahana, Tuhin
supporting information, p. 20661 - 20665 (2021/08/25)
Transformations of nitrogen-oxyanions (N...
New diarylsulfonamide inhibitors of Leishmania infantum amastigotes
González, Myriam,Alcolea, Pedro José,álvarez, Raquel,Medarde, Manuel,Larraga, Vicente,Peláez, Rafael
, p. 45 - 64 (2021/05/26)
New drugs against visceral leishmaniasis...
Methoxy and bromo scans on N-(5-methoxyphenyl) methoxybenzenesulphonamides reveal potent cytotoxic compounds, especially against the human breast adenocarcinoma MCF7 cell line
Medarde, Manuel,González, Myriam,González-Sarmiento, Rogelio,Ovejero-Sánchez, María,Peláez, Rafael,Vicente-Blázquez, Alba
, p. 1029 - 1047 (2021/06/16)
Thirty seven N-(5-methoxyphenyl)-4-metho...
Electrochemical Nitration with Nitrite
Blum, Stephan P.,Nickel, Christean,Sch?ffer, Lukas,Karakaya, Tarik,Waldvogel, Siegfried R.
, p. 4936 - 4940 (2021/10/25)
Aromatic nitration has tremendous import...
89-39-4 Process route
-
-
509-14-8
tetranitromethane
-
-
150-78-7
1,4-dimethoxybezene
-
-
517-25-9,57073-37-7
trinitromethane
-
-
89-39-4
1,4-dimethoxy-2-nitrobenzene
Conditions
| Conditions | Yield |
|---|---|
|
In
dichloromethane;
for 15h;
Product distribution;
Quantum yield;
Irradiation;
|
92%
|
-
-
150-78-7
1,4-dimethoxybezene
-
-
89-39-4
1,4-dimethoxy-2-nitrobenzene
Conditions
| Conditions | Yield |
|---|---|
|
With
Nitrogen dioxide;
In
dichloromethane;
in the dark; -78 deg C, 2 min; RT, 15 min;
|
100%
|
|
With
Nitrogen dioxide;
In
dichloromethane;
at -78 ℃;
|
100%
|
|
With
benzyltriphenylphosphonium nitrate; Methanesulfonic anhydride;
at 20 ℃;
for 0.0833333h;
|
100%
|
|
With
nitric acid; phosphorus pentoxide; silica gel;
at 20 ℃;
for 0.05h;
|
100%
|
|
With
Selectfluor; sodium nitrite;
In
acetonitrile;
at 20 ℃;
for 184h;
|
100%
|
|
With
air; nitrogen(II) oxide;
In
acetonitrile;
for 0.25h;
Ambient temperature;
|
99%
|
|
With
chloro-trimethyl-silane; copper(ll) sulfate pentahydrate; guanidine nitrate;
In
acetonitrile;
at 20 ℃;
for 12h;
|
99%
|
|
With
tert.-butylnitrite;
In
dichloromethane;
at 20 ℃;
for 6h;
Reagent/catalyst;
|
99%
|
|
With
nitric acid; silica gel;
In
dichloromethane;
for 0.0833333h;
Ambient temperature;
|
98%
|
|
With
Nitrogen dioxide;
In
dichloromethane;
at -10 ℃;
for 0.5h;
|
98%
|
|
With
3-(ethoxycarbonyl)-1-(5-methyl-5-(nitrosooxy)hexyl)pyridin-1-ium bis(trifluoromethanesulfonyl)imide;
at 20 ℃;
for 2h;
Ionic liquid;
|
97%
|
|
With
nitric acid; acetic acid;
In
dichloromethane;
at 0 ℃;
for 2h;
|
96%
|
|
With
oxygen; Nitrogen dioxide;
iron(III)-acetylacetonate;
In
1,2-dichloro-ethane;
at 0 ℃;
for 0.5h;
|
94%
|
|
With
nitric acid; acetic acid;
at 0 ℃;
for 4h;
Inert atmosphere;
|
94%
|
|
With
tetranitromethane;
In
dichloromethane;
Irradiation;
|
92%
|
|
With
copper(II) nitrate/zeolite H-Y;
at 70 - 80 ℃;
for 0.5h;
Further Variations:;
heating mode; times;
Product distribution;
|
92%
|
|
With
tert.-butylnitrite;
In
acetonitrile;
at 20 ℃;
for 1h;
Solvent;
|
92%
|
|
With
sulfuric acid; nitric acid; acetic acid;
at 25 ℃;
for 24h;
|
90%
|
|
With
(NH4)2Ce(NO3)5; acetic anhydride;
at 25 ℃;
for 14h;
|
90%
|
|
With
Zn(NO3)2*2N2O4;
In
dichloromethane;
at 20 ℃;
for 2h;
|
90%
|
|
With
copper(II) nitrate;
In
diethyl ether; acetic anhydride;
|
89%
|
|
With
1,1,1,3',3',3'-hexafluoro-propanol; tetrabutylammonium nitrite;
In
acetonitrile;
at 20 ℃;
for 0.833333h;
Solvent;
Reagent/catalyst;
Temperature;
Electrochemical reaction;
Inert atmosphere;
Green chemistry;
|
88%
|
|
With
sodium nitrate; silver nitrate; potassium nitrate;
potassium hexacyanoferrate(III);
at 160 ℃;
for 0.5h;
|
86%
|
|
With
cerium(IV) ammonium nitrate supported on silica;
In
dichloromethane;
for 0.25h;
Ambient temperature;
|
84%
|
|
With
Montmorillonite KSF; nitric acid;
hafnium oxychloride;
In
tetrahydrofuran;
at 20 ℃;
for 4h;
|
84%
|
|
With
Montmorillonite KSF; nitric acid;
bismuth(III) nitrate;
In
tetrahydrofuran;
at 20 ℃;
for 4h;
|
76%
|
|
With
Brij 35; sodium nitrite;
In
water;
at 30 ℃;
Product distribution;
Mechanism;
electrochemical reaction, also in cationic and anionic micellar media;
|
70%
|
|
With
Brij 35; sodium nitrite;
In
water;
at 30 ℃;
electrochemical reaction;
|
70%
|
|
With
ammonium cerium(IV) nitrate;
In
acetonitrile;
Ambient temperature;
|
70%
|
|
With
tetranitromethane;
In
hexane;
Product distribution;
Irradiation;
charge-transfer nitration in various solvents;
|
|
|
With
oxygen; Nitrogen dioxide;
In
dichloromethane;
at -23 ℃;
oxygen uptake;
|
|
|
With
Nitrogen dioxide;
In
dichloromethane;
at -78 ℃;
Product distribution;
Mechanism;
stoichiometry;
|
|
|
With
water; nitric acid;
|
|
|
durch Nitrierung;
|
|
|
With
nitric acid;
|
|
|
With
nitric acid; acetic acid;
|
|
|
With
nitric acid;
In
acetic acid;
|
|
|
With
nitric acid;
In
acetic acid;
at 0 - 25 ℃;
Yield given;
|
|
|
With
tetranitromethane;
In
dichloromethane;
for 4h;
Yield given;
Irradiation;
|
|
|
With
nitrate radical;
at 23.85 ℃;
under 735 Torr;
Kinetics;
|
|
|
With
trifluoromethylsulfonic anhydride; tetramethylammonium nitrate;
In
dichloromethane;
for 17h;
|
|
|
With
nitric acid;
In
water;
|
|
|
With
cerium nitrate pentahydrate;
for 0.5h;
Milling;
Green chemistry;
|
100 %Spectr.
|
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-
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-
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-
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-
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-
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-
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-
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1,2,4,5-tetrabromo-3,6-dimethoxybenzene
-
55034-12-3
6-bromo-1,4-dimethoxy-2-nitrobenzene
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